| Product Name: | 4-NITROPHENYL-BETA-D-GLUCOPYRANOSIDE |
| Synonyms: | PNP BETA-D-GLUCOPYRANOSIDE;P-NITROPHENYL-B-D-GLUCOSIDE;P-NITROPHENYL-BETA-GLUCOPYRANOSIDE;P-NITROPHENYL-BETA-GLUCOSE;P-NITROPHENYL-BETA-GLUCOSIDE;P-NITROPHENYL BETA-D-GLUCOPYRANOSIDE;P-NITROPHENYL-BETA-D-GLUCOSIDE;P-NITROPHENYL-B-D-GLUCOPYRANOSIDE |
| CAS: | 2492-87-7 |
| MF: | C12H15NO8 |
| MW: | 301.25 |
| EINECS: | 219-661-3 |
| Product Categories: | Substrates ; Biochemistry ; Glucose ; Glycosides ; Sugars ; Carbohydrates & Derivatives ; substrate |
| Mol File: | 2492-87-7.mol |
| 4-NITROPHENYL-BETA-D-GLUCOPYRANOSIDE Chemical Properties |
| Melting point | 165-168 °C |
| Boiling point | 442.39°C (rough estimate) |
| density | 1.3709 (rough estimate) |
| refractive index | -102.5 ° (C=1, H2O) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| pka | 12.55±0.70(Predicted) |
| form | Powder |
| color | White to yellow |
| Water Solubility | Soluble in water, metha nol, warm ethanol, dimethyl sulfoxide and dimethylformamide. Insoluble in ether. |
| BRN | 92211 |
| InChIKey | IFBHRQDFSNCLOZ-RMPHRYRLSA-N |
| CAS DataBase Reference | 2492-87-7(CAS DataBase Reference) |
| EPA Substance Registry System | .beta.-D-Glucopyranoside, 4-nitrophenyl (2492-87-7) |
| Safety Information |
| Hazard Codes | Xn,Xi |
| Risk Statements | 20/21/22-68/20/21/22-36/37/38-68 |
| Safety Statements | 36/37-36-26-60-33-22 |
| WGK Germany | 3 |
| F | 3-10-21 |
| TSCA | Yes |
| HS Code | 29400090 |
| MSDS Information |
| 4-NITROPHENYL-BETA-D-GLUCOPYRANOSIDE Usage And Synthesis |
| Chemical Properties | White Crystals |
| Definition | ChEBI: A beta-D-glucoside that is beta-D-glucopyranose in which the anomeric hydroxy hydrogen is replaced by a 4-nitrophenyl group. |
| Purification Methods | Purify 4-nitrophenyl--D-glucopyranoside by recrystallisation from EtOH or H2O. [Montgomery et al. J Am Chem Soc 64 690 1942, Snyder & Link J Am Chem Soc 75 1758 1953.] It is a chromogenic substrate for -glucosidases [Weber & Fink J Biol Chem 255 9030 1980]. [Beilstein 17/7 V53.] |
| 4-NITROPHENYL-BETA-D-GLUCOPYRANOSIDE Preparation Products And Raw materials |
| Raw materials | Ethanol --> Sodium hydroxide --> Ethyl acetate --> Metha nol --> Dichloromethane --> Sodium --> Magnesium sulfate --> Acetic anhydride --> Triethylamine --> Sodium bicarbonate --> Sodium acetate --> D(+)-Glucose --> Boron trifl uoride diethyl etherate --> Butyl acetate --> 4-Nitrophenol --> AMBERLYST(R) 15 --> 4-NITROPHENYL-ALPHA-D-GLUCOPYRANOSIDE |
| Preparation Products | rhodiocyanoside A |